JEE Advanced 2014
JEE Advanced 2014 Chemistry Syllabus Physical chemistry
General topics: conception of atoms and molecules; Dalton’s atomic
theory; Mole concept; Chemical formulae; Balanced chemical equations;
Calculations (based on mole concept) involving common oxidoreduction,
neutralisation, and displacement reactions; Concentration in terms of
mole fraction, molarity, concentration and normality.
Gaseous
and liquid states: temperature scale of temperature, gas equation;
Deviation from quality, van der Waals equation; kinetic theory of gases
of gases, average, root mean sq. and most probable velocities and their
relation with temperature; Law of partial pressures; Vapour pressure;
Diffusion of gases.
Atomic structure and chemical bonding: Bohr
model, spectrum of atom, quantum numbers; property, Broglie hypothesis;
Uncertainty principle; Qualitative quantum mechanical image of atom,
shapes of s, p and d orbitals; Electronic configurations of parts (up to
number 36); Aufbau principle; Pauli’s law of nature and Hund’s rule;
Orbital overlap and valence bond; sexual union involving s, p and d
orbitals only; Orbital energy diagrams for homonuclear matter species;
chemical element bond; Polarity in molecules, moment (qualitative
aspects only); VSEPR model and shapes of molecules (linear, angular,
triangular, sq. tabular, pyramidal, sq. pointed, symmetrical
bipyramidal, tetrahedral and octahedral).
Energetics: initial
law of thermodynamics; Internal energy, work and warmth, pressure-volume
work; heat content, Hess’s law; Heat of reaction, fusion and
vapourization; Second law of thermodynamics; Entropy; Free energy;
Criterion of naturalness.
Chemical equilibrium: Law of mass
action; constant, lupus erythematosus Chatelier’s principle (effect of
concentration, temperature and pressure); Significance of ΔG and ΔG° in
chemical equilibrium; Solubility product, common particle impact,
hydrogen ion concentration and buffer solutions; Acids and bases
(Bronsted and Lewis concepts); reaction of salts.
Electrochemistry: chemical science cells and cell reactions; normal
conductor potentials; chemist equation and its relevancy ΔG;
electromotive force series, electrical phenomenon of galvanic cells;
Faraday’s laws of electrolysis; Electrolytic electrical phenomenon,
specific, equivalent and molar conduction, Kohlrausch’s law;
Concentration cells.
Chemical kinetics: Rates of chemical
reactions; Order of reactions; Rate constant; initial order reactions;
Temperature dependence of rate constant (Arrhenius equation).
Solid state: Classification of solids, crystalline state, seven crystal
systems (cell parameters a, b, c, α, β, γ), shut packed structure of
solids (cubic), packing in independent agency, bcc and hcp lattices;
Nearest neighbours, ionic radii, straightforward ionic compounds,
purpose defects.
Solutions: Raoult’s law; mass determination
from lowering of pressure level, elevation of boiling purpose and
depression of temperature.
Surface chemistry: Elementary ideas
of surface assimilation (excluding surface assimilation isotherms);
Colloids: varieties, strategies of preparation and general properties;
Elementary concepts of emulsions, surfactants and micelles (only
definitions and examples).
Nuclear chemistry: Radioactivity:
isotopes and isobars; Properties of α, β and γ rays; mechanics of
disintegration (decay series excluded), carbon dating; Stability of
nuclei with reference to proton-neutron ratio; transient discussion on
fission and fusion reactions.
JEE Advanced 2014 Chemistry info
Inorganic Chemistry
Isolation/preparation and properties of the subsequent non-metals:
element, silicon, nitrogen, phosphorus, oxygen, sulphur and halogens;
Properties of allotropes of carbon (only diamond and graphite),
phosphorus and sulphur.
Preparation and properties of the
subsequent compounds: Oxides, peroxides, hydroxides, carbonates,
bicarbonates, chlorides and sulphates of metallic element, potassium,
metallic element and calcium; Boron: diborane, chemical element acid and
borax; Aluminium: corundom, chloride and alums; Carbon: oxides and acid
(carbonic acid); Silicon: silicones, silicates and semiconductor
carbide; Nitrogen: oxides, oxyacids and ammonia; Phosphorus: oxides,
oxyacids (phosphorus acid, phosphorous acid) and phosphine; Oxygen: gas
and chemical element peroxide; Sulphur: chemical element compound,
oxides, sulphurous acid, vitriol and metallic element thiosulphate;
Halogens: hydrohalic acids, oxides and oxyacids of halogen, bleaching
powder; chemical element fluorides.
Transition parts (3d
series): Definition, general characteristics, reaction states and their
stabilities, color (excluding the small print of electronic transitions)
and calculation of spin-only magnetic moment; Coordination compounds:
terminology of mononucleate coordination compounds, cis-trans and
ionisation isomerisms, crossbreeding and geometries of mononucleate
coordination compounds (linear, tetrahedral, sq. tabular and
octahedral).
Preparation and properties of the subsequent
compounds: Oxides and chlorides of tin and lead; Oxides, chlorides and
sulphates of Fe2+, Cu2+ and Zn2+; permanganate of potash, salt, silver
compound, nitrate, silver thiosulphate.
Ores and minerals:
ordinarily occurring ores and minerals of iron, copper, tin, lead,
magnesium, aluminium, metallic element and silver.
Extractive
metallurgy: Chemical principles and reactions solely (industrial details
excluded); Carbon reduction technique (iron and tin); Self reduction
technique (copper and lead); Electrolytic reduction technique (magnesium
and aluminium); industrial process (silver and gold).
Principles of qualitative analysis: teams I to V (only Ag+, Hg2+, Cu2+,
Pb2+, Bi3+, Fe3+, Cr3+, Al3+, Ca2+, Ba2+, Zn2+, Mn2+ and Mg2+); Nitrate,
halides (excluding fluoride), sulfate and compound.
JEE Advanced 2014 Chemistry info
Organic Chemistry
Concepts: sexual union of carbon; letter and pi-bonds; Shapes of easy
organic molecules; Structural and geometrical state; Optical isomerism
of compounds containing up to 2 uneven centres, (R,S andE,Z terminology
excluded); IUPAC terminology of easy organic compounds (only
hydrocarbons, mono-functional and bi-functional compounds);
Conformations of alkane and alkane series (Newman projections);
Resonance and hyperconjugation; Keto-enol tautomerism; Determination of
empirical and molecular formulae of easy compounds (only combustion
method); chemical element bonds: definition and their effects on
physical properties of alcohols and radical acids; Inductive and
resonance effects on acidity and basicity of organic acids and bases;
Polarity and inductive effects in radical halides; Reactive
intermediates made throughout homolytic and heterolytic bond cleavage;
Formation, structure and stability of carbocations, carbanions and free
radicals.
Preparation, properties and reactions of alkanes:
Homologous series, physical properties of alkanes (melting points,
boiling points and density); Combustion and halogenation of alkanes;
Preparation of alkanes by Wurtz reaction and chemical action reactions.
Preparation, properties and reactions of alkenes and alkynes: Physical
properties of alkenes and alkynes (boiling points, density and dipole
moments); Acidity of alkynes; Acid catalysed association of alkenes and
alkynes (excluding the stereochemistry of addition and elimination);
Reactions of alkenes with KMnO4 and ozone; Reduction of alkenes and
alkynes; Preparation of alkenes and alkynes by elimination reactions;
Electrophilic addition reactions of alkenes with X2, HX, HOX (X=halogen)
and H2O; Addition reactions of alkynes; Metal acetylides.
Reactions of benzene: Structure and aromaticity; Electrophilic
substitution reactions: halogenation, nitration, sulphonation,
Friedel-Crafts alkylation and acylation; impact of o-, m- and
p-directing teams in monosubstituted benzenes.
Phenols: Acidity,
electrophilic substitution reactions (halogenation, nitration and
sulphonation); Reimer-Tieman reaction, Kolbe reaction.
Characteristic reactions of the subsequent (including those mentioned
above): radical halides: arrangement reactions of radical carbocation,
Grignard reactions, nucleophilic substitution reactions; Alcohols:
esterification, dehydration and reaction, reaction with metallic
element, phosphorus halides, ZnCl2/concentrated HCl, conversion of
alcohols into aldehydes and ketones; Ethers:Preparation by Williamson’s
Synthesis; Aldehydes and Ketones: reaction, reduction, organic compound
and hydrazone formation; organic compound condensation, Perkin
reaction; Cannizzaro reaction; alkyl halide reaction and nucleophilic
addition reactions (Grignard addition); radical acids: formation of
esters, acid chlorides and amides, organic compound hydrolysis; Amines:
basicity of substituted anilines and acyclic amines, preparation from
nitro compounds, reaction with acid, radical coupling reaction of cation
salts of aromatic amines, Sandmeyer and connected reactions of cation
salts; carbylamine reaction; Haloarenes: nucleophilic aromatic
substitution in haloarenes and substituted haloarenes (excluding Benzyne
mechanism and Cine substitution).
Carbohydrates:
Classification; mono- and di-saccharides (glucose and sucrose);
reaction, reduction, organic compound formation and reaction of plant
product.
Amino acids and peptides: General structure (only primary structure for peptides) and physical properties.
Properties and uses of some vital polymers: Natural rubber, cellulose, nylon, teflon and PVC.
Practical organic chemistry: Detection of parts (N, S, halogens);
Detection and identification of the subsequent purposeful groups: group
(alcoholic and phenolic), carbonyl (aldehyde and ketone), carboxyl,
amino and nitro; Chemical strategies of separation of mono-functional
organic compounds from binary mixtures.JEE Advanced 2014 Mathematics Syllabus CLICK HERE